Sodium Acetate → Acetic acid, yttrium(3+) salt (3:1)

HRID 1742165

Reaktionsgleichung

Reaktionsgleichung von HRID 1742165
[Cl-].[Y+3:2].[Cl-].[Cl-].[C:5]([O-:8])(=[O:7])[CH3:6].[Na+]>[2H]O[2H]>[C:5]([O-:8])(=[O:7])[CH3:6].[Y+3:2].[C:5]([O-:8])(=[O:7])[CH3:6].[C:5]([O-:8])(=[O:7])[CH3:6]

Komponenten

4

Edukt 2

HCID 517045Sodium AcetateHCID 10198055Yttrium trichloride

Produkt 1

HCID 168102Acetic acid, yttrium(3+) salt (3:1)

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 24602Deuterium OxideLösungsmittel2×

Versuchsvorschrift

The same experimental methods were used for this study as were used for Example 8. The starburst polyamidoamine methylene-carboxylate terminated material (0.40g 62.5% active, remainder sodium bromide, 0.12 mmol.) was dissolved in 4-5 ml of deuterium oxide. The resultant pH was 11.5-12, which was lowered to 9.4 with 6 N HC1 prior to the experiment. A solution of yttrium acetate was prepared by dissolving yttrium chloride (0.1125g, .37 mmol.) and sodium acetate (0.0915g, 1.1 mmol.) in 1.5 ml of deuterium oxide, thus every 0.5 ml of solution contains one mole equivalent of metal.

Quellen und Nachweise

ORD-Eintrag
ord-ea39205b6a2b4cee8efbdbd7cf5b4a20
Quelldatensatz
uspto-grants-1994_08
Patentnummer
US05338532

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