Triglycidylglycerol → 1,2,3-Tris[3-(4-benzoyloxy-2,2,6,6-tetramethylpiperidino)-2-hydroxypropoxy]propane

HRID 1758191

Reaktionsgleichung

Reaktionsgleichung von HRID 1758191
[C:1]([O:9][CH:10]1[CH2:15][C:14]([CH3:17])([CH3:16])[NH:13][C:12]([CH3:19])([CH3:18])[CH2:11]1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[O:20]1[CH2:37][CH:21]1[CH2:22][O:23][CH2:24][CH:25]([CH2:31][O:32][CH2:33][CH:34]1[O:36][CH2:35]1)[O:26][CH2:27][CH:28]1[O:30][CH2:29]1>>[C:1]([O:9][CH:10]1[CH2:15][C:14]([CH3:17])([CH3:16])[N:13]([CH2:35][CH:34]([OH:36])[CH2:33][O:32][CH2:31][CH:25]([O:26][CH2:27][CH:28]([OH:30])[CH2:29][N:13]2[C:14]([CH3:17])([CH3:16])[CH2:15][CH:10]([O:9][C:1](=[O:8])[C:2]3[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=3)[CH2:11][C:12]2([CH3:19])[CH3:18])[CH2:24][O:23][CH2:22][CH:21]([OH:20])[CH2:37][N:13]2[C:12]([CH3:19])([CH3:18])[CH2:11][CH:10]([O:9][C:1](=[O:8])[C:2]3[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=3)[CH2:15][C:14]2([CH3:17])[CH3:16])[C:12]([CH3:19])([CH3:18])[CH2:11]1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Komponenten

3

Edukt 2

HCID 25795TriglycidylglycerolHCID 5799672,2,6,6-Tetramethyl-4-piperidyl benzoate

Produkt 1

HCID 205105911,2,3-Tris[3-(4-benzoyloxy-2,2,6,6-tetramethylpiperidino)-2-hydroxypropoxy]propane

Versuchsvorschrift

A mixture of 10.1 g of 4-benzoyloxy-2,2,6,6-tetramethylpiperidine and 2.6 g of glycerol tris(2,3-epoxypropyl)ether was reacted following the procedure described in Example 5 to give the desired Compound No. 115 in the form of a white vitreous solid having an Rf value of 0.87 on thin-layer chromatography on silica gel developed with a 4:1 by volume mixture of ethyl acetate and triethylamine.

Aufarbeitung

  1. customwas reacted

Quellen und Nachweise

ORD-Eintrag
ord-18a88326651540f8aad31d676b6135b5
Quelldatensatz
uspto-grants-1983_02
Patentnummer
US04371644

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