4-{[(2,2-Dichlorocyclopropyl)methyl]sulfanyl}-2-nitroaniline → HCID 20532837, Verbindung

HRID 1758885Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1758885
[Cl:1][C:2]1([Cl:17])[CH2:4][CH:3]1[CH2:5][S:6][C:7]1[CH:13]=[CH:12][C:10]([NH2:11])=[C:9]([N+:14]([O-])=O)[CH:8]=1>C(O)C.O=[Pt]=O>[Cl:17][C:2]1([Cl:1])[CH2:4][CH:3]1[CH2:5][S:6][C:7]1[CH:13]=[CH:12][C:10]([NH2:11])=[C:9]([NH2:14])[CH:8]=1

Komponenten

4

Edukt 1

HCID 205328394-{[(2,2-Dichlorocyclopropyl)methyl]sulfanyl}-2-nitroaniline

Produkt 1

HCID 20532837HCID 20532837, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 345198Adams' catalystKatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

A mixture of 8.8 g (0.03 mole) of 4-[(2,2-dichlorocyclopropyl)methyl]thio-2-nitroaniline and 0.6 g of PtO2 in 200 ml of absolute ethanol is reduced on the Parr hydrogenator at 50 psi until the theoretical amount of H2 is absorbed. The mixture is filtered and the solvent is removed in vacuo to yield a dark oil.

Aufarbeitung

  1. customis absorbed
  2. filtrationThe mixture is filtered
  3. customthe solvent is removed in vacuo
  4. customto yield a dark oil

Quellen und Nachweise

ORD-Eintrag
ord-2c27ae431c834ea794f295e899e894f4
Quelldatensatz
uspto-grants-1982_07
Patentnummer
USRE030990

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