HCID 178420439, Verbindung → HCID 178527984, Verbindung

HRID 1759030

Reaktionsgleichung

Reaktionsgleichung von HRID 1759030
C([S:8][C:9]1[N:10]=[N:11][N:12]([CH2:14][C:15]2[NH:19][N:18]=[N:17][N:16]=2)[N:13]=1)C1C=CC=CC=1>[Hg].CN(C=O)C>[NH:16]1[C:15]([CH2:14][N:12]2[N:11]=[N:10][C:9]([SH:8])=[N:13]2)=[N:19][N:18]=[N:17]1

Komponenten

4

Edukt 1

HCID 178420439HCID 178420439, Verbindung

Produkt 1

HCID 178527984HCID 178527984, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23931MercuryKatalysatorHCID 6228DimethylformamideLösungsmittel

Versuchsvorschrift

5-Benzylthio-2-(1H-tetrazole-5-ylmethyl)-2H-tetrazole, 175 mg., prepared as described above under part C, was dissolved in 40 ml. of distilled DMF and reduced at the mercury pool cathode (14 cm2Hg pool) with a platinium wire anode. The electrodes were separated by a glass frit. The electrolyte was tetraethylammonium perchlorate, 0.1 M in the DMF solution of the substrate. The electrolysis was carried out at -2.7 to -2.85 volts for 500 seconds and at -2.80 v. for about 630 seconds.

Aufarbeitung

  1. custom, prepared
  2. dissolutionwas dissolved in 40 ml
  3. customThe electrodes were separated by a glass frit
  4. waitfor about 630 seconds

Quellen und Nachweise

ORD-Eintrag
ord-ee1b74901d1e40fbbf63b0f57dd92f72
Quelldatensatz
uspto-grants-1982_07
Patentnummer
US04338452

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