Homoallyl bromide → 4-Bromobutyldimethylchlorosilane

Temperatur

60 °C

Hexachloroplatinic acid hexahydrate (0.02 g, 0.039 mmole) was dissolved in a minimum of 2-propanol. This solution was dissolved in 75 ml toluene under argon. 2-propanol and water were removed by azeotropically distilling 25 ml of the toluene. The resulting solution was stirred and 6.17 g (0.046 mole) of 4-bromo-1-butene was added at 40° C. 4.32 g (0.046 mole) of dimethylchlorosilane was slowly added and the solution was heated to 60° C. and allowed to react for four hours. The mixture was distilled to remove the toluene. Further vacuum distillation yielded 8.0 g of product with a b.p. of 92°-95° C. at 5 mm Hg pressure. 'H NMR confirmed the structure.

1. custom2-propanol and water were removed
2. distillationby azeotropically distilling 25 ml of the toluene
3. customto react for four hours
4. distillationThe mixture was distilled
5. customto remove the toluene
6. distillationFurther vacuum distillation

ORD-Eintrag

ord-a15d1ae6b3414632a1b2c5cd706dd8db

Quelldatensatz

uspto-grants-1989_05

DOI

10.6084/m9.figshare.5104873.v1

Patentnummer

US04833262