Tert-Butylamine → HCID 20309482, Verbindung
Reaktionsgleichung
[O:1]1[CH2:21][CH:2]1[CH2:3][O:4][C:5]1[CH:18]=[CH:17][C:16]([O:19][CH3:20])=[CH:15][C:6]=1[C:7]([CH2:9][CH2:10][C:11]([O:13][CH3:14])=[O:12])=[O:8].[C:22]([NH2:26])([CH3:25])([CH3:24])[CH3:23]>>[C:22]([NH:26][CH2:21][CH:2]([OH:1])[CH2:3][O:4][C:5]1[CH:18]=[CH:17][C:16]([O:19][CH3:20])=[CH:15][C:6]=1[C:7]([CH2:9][CH2:10][C:11]([O:13][CH3:14])=[O:12])=[O:8])([CH3:25])([CH3:24])[CH3:23]Komponenten
3
Versuchsvorschrift
Methyl 3-[2-(2,3-epoxypropoxy)-5-methoxybenzoyl]-propionate was reacted with t-butylamine in a similar manner to that described in Example 2 (i) to give methyl 3-[2-(3-t-butylamino-2-hydroxypropoxy)-5-methoxybenzoyl]-propionate, which recrystallised from ether, had m.p. 70° - 72° C. (Found: C, 62.22; H, 8.22; N, 3.65; C19H29NO6 requires: C, 62.10; H, 7.96; N, 3.81%)
Quellen und Nachweise
- ORD-Eintrag
- ord-786dfa9b1b5d453098497899808b9bf6
- Quelldatensatz
- uspto-grants-1978_09
- Patentnummer