Triethylamine → 3-Nitrooxy-propyl 5-nitrooxy-hexanoate
Reaktionsgleichung
[N+:1]([O:4][CH2:5][CH2:6][CH2:7][OH:8])([O-:3])=[O:2].[CH2:9](N(CC)CC)C.[N+:16]([O:19][CH2:20][CH2:21][CH2:22][CH2:23][C:24](Cl)=[O:25])([O-:18])=[O:17]>C(OCC)C>[N+:16]([O:19][CH:20]([CH3:9])[CH2:21][CH2:22][CH2:23][C:24]([O:8][CH2:7][CH2:6][CH2:5][O:4][N+:1]([O-:3])=[O:2])=[O:25])([O-:18])=[O:17]Komponenten
5
Edukt 3
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
20 mmol 3-Nitrooxypropanol dissolved in 10 ml Diethylether and 20 mmol Triethylamine were cooled to 0° C. 18.2 mmol 5-nitrooxypentoylchlorid were dropped over a period of 5 min at 0 to 5° C. After stirring over night without cooling, the reaction mixture was extracted with 1N HCl, twice with water, washed with brine, dried over Na2SO4 and the solvent was removed in vacuo.