Hydrochloric Acid → HCID 58128537, Verbindung

HRID 1798805Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1798805
C1(S[C:5]2[CH:10]=[CH:9][C:8]([O:11][CH3:12])=[CH:7][CH:6]=2)CC1.O[O:14][S:15]([O-:17])=O.[K+].Cl.C(O[CH2:24][CH3:25])(=O)C.[CH3:26]O>O>[CH:25]1([S:15]([C:5]2[CH:6]=[CH:7][C:8]([O:11][CH3:12])=[CH:9][CH:10]=2)(=[O:17])=[O:14])[CH2:24][CH2:26]1

Komponenten

7

Edukt 5

HCID 313Hydrochloric AcidHCID 887MethanolHCID 8857Ethyl AcetateHCID 126929601-(Cyclopropylthio)-4-methoxybenzeneHCID 23707502Potassium hydroxy sulfite

Produkt 1

HCID 58128537HCID 58128537, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

1-(cyclopropylthio)-4-methoxybenzene (300 mg, 1.66 mmol) was dissolved in 8 mL MeOH and Water (1:1). Oxone (4.9 g, 6.66 mmol) was added and the mixture was stirred overnight. 1N HCl was used to dissolve the salts and ethyl acetate was added to extract the product. The organic extract was washed with 1N HCl (3×) and brine, dried over sodium sulfate, and the solvent was removed under reduced pressure to obtain the crude product which is used without further purification.

Aufarbeitung

  1. additionwas added
  2. extractionto extract the product
  3. extractionThe organic extract
  4. washwas washed with 1N HCl (3×) and brine
  5. dry with materialdried over sodium sulfate
  6. customthe solvent was removed under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-db6dadd1b29d4c5ba5dd41448dc6262f
Quelldatensatz
uspto-grants-2013_01
Patentnummer
US08343990B2

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