HCID 86158515, Verbindung → HCID 19372161, Verbindung
Reaktionsgleichung
[CH3:1][O:2][C:3](=[O:22])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][N:19]=[N+]=[N-]>CO.[Pd]>[CH3:1][O:2][C:3](=[O:22])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][NH2:19]Komponenten
4
Reagenzien, Katalysatoren, Lösungsmittel 2
Versuchsvorschrift
16-azidohexadecanoic acid methyl ester is catalytically hydrogenated with palladium/activated charcoal in methanol at 3 bar for three hours to give the corresponding amine (Zinic et al., Positionally Isomeric Organic Gelators: Structure-Gelation Study, Racemic versus Enantiomeric Gelators, and Solvation Effects, Chem. Eur. J. 2010; 16:3066-82).
Quellen und Nachweise
- ORD-Eintrag
- ord-4e127cdbee584fd48a1f74d53939a02e
- Quelldatensatz
- uspto-grants-2015_02
- Patentnummer
- US08945897B2
Notizen zur Reaktion
Wird geladen…