Hydrogen Peroxide → 6-hydroxy-4-methylbenzo[d]oxazol-2(3H)-one

HRID 1846417Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1846417
[CH3:1][C:2]1[C:7]2[NH:8][C:9](=[O:11])[O:10][C:6]=2[CH:5]=[C:4]([O:12]B(O)O)[CH:3]=1.OO>C(O)(=O)C>[OH:12][C:4]1[CH:3]=[C:2]([CH3:1])[C:7]2[NH:8][C:9](=[O:11])[O:10][C:6]=2[CH:5]=1

Komponenten

4

Edukt 2

HCID 784Hydrogen PeroxideHCID 669782724-Methyl-2-oxo-2,3-dihydrobenzo[d]oxazol-6-ylboric acid

Produkt 1

HCID 669780936-hydroxy-4-methylbenzo[d]oxazol-2(3H)-one

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 176Acetic AcidLösungsmittel

Versuchsvorschrift

77 mg (0.40 mmol) 4-methyl-2-oxo-2,3-dihydrobenzo[d]oxazol-6-ylboric acid were dissolved in 2.0 mL glacial acetic acid and mixed with 0.20 mL (2.3 mmol) hydrogen peroxide solution (35% in water) and stirred briefly. The reaction mixture was left to stand for 1 h at RT. The precipitate formed was suction filtered, washed with water and dried i. vac.

Aufarbeitung

  1. waitThe reaction mixture was left
  2. customThe precipitate formed
  3. filtrationfiltered
  4. washwashed with water
  5. customdried i

Quellen und Nachweise

ORD-Eintrag
ord-ae0a62c06edc422f8e8d1e65b131a93d
Quelldatensatz
uspto-grants-2015_02
Patentnummer
US08952014B2

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