HCID 53911873, Verbindung → HCID 54540261, Verbindung

HRID 1856498Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1856498
[N+:1]([CH2:4][CH2:5][CH2:6][CH2:7][O:8][C:9](=[O:25])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])([O-])=O>CCO.C1COCC1.[Zn]>[NH2:1][CH2:4][CH2:5][CH2:6][CH2:7][O:8][C:9](=[O:25])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]

Komponenten

4

Edukt 1

HCID 53911873HCID 53911873, Verbindung

Produkt 1

HCID 54540261HCID 54540261, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23994ZincKatalysatorHCID 21873804Tetrahydrofuran ethanolLösungsmittel

Versuchsvorschrift

Hexadecanoic acid (4-nitrobutyl)ester was reduced with zinc in EtOH/THF/6 nHCl for 30 minutes at 35°-35°. Work up in the cold via basification with ammonia and extraction with methylene chloride yielded a crude residue. Crystallization from ether furnished off-white crystals, m.p. 59°-61°.

Aufarbeitung

  1. extractionwith ammonia and extraction with methylene chloride

Quellen und Nachweise

ORD-Eintrag
ord-650418e33a3c4bb88c6f6af3c4b56a85
Quelldatensatz
uspto-grants-1980_08
Patentnummer
US04219660

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