Ammonia → Dimorpholinodiethyl ether

HRID 1873059Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1873059
[NH:1]1[CH2:6][CH2:5][O:4][CH2:3][CH2:2]1.[NH3:7].[CH2:8](O)[CH2:9][O:10][CH2:11][CH2:12]O>[Ni]>[O:4]1[CH2:5][CH2:6][N:1]([CH2:2][CH2:3][O:4][CH2:5][CH2:6][N:7]2[CH2:8][CH2:9][O:10][CH2:11][CH2:12]2)[CH2:2][CH2:3]1

Komponenten

5

Edukt 3

HCID 222AmmoniaHCID 8083MorpholineHCID 8117Diethylene Glycol

Produkt 1

HCID 80900Dimorpholinodiethyl etherAusbeute 70 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 935NickelKatalysator

Versuchsvorschrift

Zh. Vses. Khim. Obshchest. 14(5), 589-90 (1969) (Chem. Abstr. 72: 66879m) describes the formation of morpholine in a yield of 70% by gas-phase reaction of diethylene glycol with NH3 over a nickel catalyst in the presence of H2. Among other by-products, bis(2-morpholinoethyl) ether was isolated in a yield of from 5 to 7%.

Quellen und Nachweise

ORD-Eintrag
ord-3278b2f9beac4cf79bbd79851045d4a1
Quelldatensatz
uspto-grants-2000_08
Patentnummer
US06111100

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