Ceric ammonium nitrate → HCID 42598871, Verbindung
Reaktionsgleichung
[OH:1][C:2]1[C:3]([CH3:20])=[C:4]2[C:9](=[C:10]([CH3:13])[C:11]=1[CH3:12])[O:8][C:7]([CH3:19])([C:14]([N:16]([CH3:18])[CH3:17])=[O:15])[CH2:6][CH2:5]2.[O:21]=[N+]([O-])[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[Ce+4].[NH4+].[NH4+]>>[OH:21][C:7]([CH3:19])([CH2:6][CH2:5][C:4]1[C:9](=[O:8])[C:10]([CH3:13])=[C:11]([CH3:12])[C:2](=[O:1])[C:3]=1[CH3:20])[C:14]([N:16]([CH3:18])[CH3:17])=[O:15]Komponenten
3
Versuchsvorschrift
Oxidation as described in protocol B, using 138.6 mg (0.50 mmol) of 6-hydroxy-N,N,2,5,7,8-hexamethylchroman-2-carboxamide and 560 mg CAN (1.02 mmol) yielded 139.9 mg of 2-hydroxy-N,N,2-trimethyl-4-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)butanamide as a yellow oil.
Quellen und Nachweise
- ORD-Eintrag
- ord-24823e56a0e1409296d033cce4a122c4
- Quelldatensatz
- uspto-grants-2013_08