Ammonium nitrate → Cobalt(2+) bis(7,7-dimethyloctanoate)

HRID 1903696Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1903696
[Co:1].[C:2]([OH:13])(=[O:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]([CH3:11])([CH3:10])[CH3:9].C([O-])=O.[Na+].[N+]([O-])([O-])=O.[NH4+]>O>[C:2]([O-:13])(=[O:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]([CH3:9])([CH3:10])[CH3:11].[Co+2:1].[C:2]([O-:13])(=[O:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]([CH3:9])([CH3:10])[CH3:11]

Komponenten

6

Edukt 4

HCID 22985Ammonium nitrateHCID 62838Versatic 10HCID 104730CobaltHCID 2723810Sodium Formate

Produkt 1

HCID 21972107Cobalt(2+) bis(7,7-dimethyloctanoate)

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Reaktionsbedingungen

Temperatur
85 °C

Versuchsvorschrift

A mixture of 50 grams of cobalt powder, 316.2 grams (1.697 moles) of neodecanoic acid (acid number, 301), a catalyst solution prepared by dissolving 5 grams of sodium formate and 5 grams of ammonium nitrate in 30 grams of water, and 130 grams of mineral spirits was heated at 85° C. for 7 hours while it was sparged with air at the rate of 30 liters per hour. The reaction mixture was heated at 135° C. under vacuum to remove water from it, filtered, and diluted with mineral spirits. There was obtained a solution of cobalt neodecanoate in mineral spirits that contained 10% cobalt and had an acid number of 18.

Aufarbeitung

  1. customa catalyst solution prepared
  2. customwas sparged with air at the rate of 30 liters per hour
  3. temperatureThe reaction mixture was heated at 135° C. under vacuum
  4. customto remove water from it
  5. filtrationfiltered
  6. additiondiluted with mineral spirits

Quellen und Nachweise

ORD-Eintrag
ord-e38f138075104e7b9ecf053bf7bae127
Quelldatensatz
uspto-grants-1984_03
Patentnummer
US04438038

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