3-methoxy-6-methyl-4-nitropyridazine 1-oxide → HCID 21766149, Verbindung

HRID 1907822Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1907822
[CH3:1][O:2][C:3]1[N:4]=[N+:5]([O-:13])[C:6]([CH3:12])=[CH:7][C:8]=1[N+]([O-])=O.[CH3:14][O-:15].[Na+]>CO>[CH3:1][O:2][C:3]1[N:4]=[N+:5]([O-:13])[C:6]([CH3:12])=[CH:7][C:8]=1[O:15][CH3:14]

Komponenten

4

Edukt 2

HCID 64053053-methoxy-6-methyl-4-nitropyridazine 1-oxideHCID 10942334Sodium Methoxide

Produkt 1

HCID 21766149HCID 21766149, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

3-Methoxy-6-methyl-4-nitropyridazine 1-oxide (1 g) was converted and worked up analogously to example 1 g). Chromatography of the crude product was unnecessary. The solvent used was methanol (30 ml), and the base sodium methoxide (as 30% solution in methanol, 1.1 ml). Yield: 900 mg LC-MS Rt: 0.29 min [M+H]+:171.1

Quellen und Nachweise

ORD-Eintrag
ord-73fa67287c55470cb6a518fcc5adc71e
Quelldatensatz
uspto-grants-2013_12
Patentnummer
US08598177B2

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