Isopropyl iodide → 9H-Fluorene, 9-(1-methylethyl)-

HRID 1918426Notizen

Reaktionsgleichung

[CH:1]1[C:13]2[CH2:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.[Li][CH2:15][CH2:16][CH2:17]C.IC(C)C.OC1O[C@@H](CO)[C@H](O)[C@H](O)[C@H]1O>>[CH:16]([CH:12]1[C:11]2[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=2[C:5]2[C:13]1=[CH:1][CH:2]=[CH:3][CH:4]=2)([CH3:17])[CH3:15]

Komponenten

Edukt 4

HCID 6362Isopropyl iodide

HCID 6853Fluorene

HCID 10219674L-Altrose

HCID 178418339Butyllithium

Produkt 1

HCID 186969H-Fluorene, 9-(1-methylethyl)-

Versuchsvorschrift

Fluorene (15.0 g, 90.4 mmol), n-BuLi (48.1 ml, 120 mmol, 2.5 M in hexane), RX=2-iodopropane (14.0 ml, 139.6 mmol). 42 was isolated as a yellowish solid (18.7 g, quant.). The analytical data were identical with these to be found in the literature (M. A. Schmidt, H. G. Alt, W. Milius, J. Organomet. Chem. 1996, 525, 15).

Aufarbeitung

custom42 was isolated as a yellowish solid (18.7 g, quant.)

Quellen und Nachweise

ORD-Eintrag: ord-7e148871503b46838dc84cee25182137
Quelldatensatz: uspto-grants-2013_12
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US08618328B2

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