Diethyl Ether → Tetraglyme

HRID 1975842Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1975842
[Cl-].[In+3:2].[Cl-].[Cl-].[CH2:5]([Mg]I)[CH3:6].[CH3:9][O:10][CH2:11][CH2:12][O:13][CH2:14][CH2:15][O:16][CH2:17][CH2:18][O:19][CH2:20][CH2:21][O:22][CH3:23].C(O[CH2:27][CH3:28])C>>[CH2:27]([In:2]([CH2:5][CH3:6])[CH2:20][CH3:21])[CH3:28].[CH3:23][O:22][CH2:21][CH2:20][O:19][CH2:18][CH2:17][O:16][CH2:15][CH2:14][O:13][CH2:12][CH2:11][O:10][CH3:9]

Komponenten

6

Edukt 4

HCID 3283Diethyl EtherHCID 8925TetraglymeHCID 159675indium(III)chlorideHCID 178461634HCID 178461634, Verbindung

Produkt 2

HCID 8925TetraglymeHCID 101912Indium, triethyl-

Versuchsvorschrift

By a procedure substantially similar to that of Example 3, an adduct of triethyl indium (TEI) and diethyl ether was prepared from indium (III) chloride and ethyl magnesium iodide. To this adduct sufficient tetraglyme was added to give a molar ratio of TEI to tetraglyme was 3:1. Diethyl ether was removed in vacuo at a bottom temperature of 74° C. Subsequently, pure TEI was obtained via dissociation of the adduct at 74°-115° C. and a pressure of <1 mbar. The TEI thereby obtained was subsequently subjected to fractional distillation at a pressure of <1 mbar. No metal impurities could be detected by ICP-OES in the distilled TEI.

Quellen und Nachweise

ORD-Eintrag
ord-b624197f2c6741e58d87e491b5e6b281
Quelldatensatz
uspto-grants-1994_02
Patentnummer
US05288885

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