Hydrazine hydrate (1:1) → (1S,8R)-1,11,11-Trimethyl-5-(3-methyl-butyl)-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2,4,6-triene
Reaktionsgleichung
[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4](=O)[C:3]2=O.COP([CH2:19][C:20](=O)[CH2:21][CH2:22][CH:23]([CH3:25])[CH3:24])(=O)OC.O.[NH2:28][NH2:29]>>[CH3:1][C@@:2]12[C:8]([CH3:10])([CH3:9])[C@@H:5]([CH2:6][CH2:7]1)[C:4]1[C:3]2=[N:28][N:29]=[C:20]([CH2:21][CH2:22][CH:23]([CH3:25])[CH3:24])[CH:19]=1Komponenten
4
Versuchsvorschrift
yellow solid. MS (ESI): 259.0 (MH+). Prepared from (1S,4R)-1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione, (5-methyl-2-oxo-hexyl)-phosphonic acid dimethyl ester, hydrazine monohydrate.