4-(Trimethylsilyl)phenylboronic Acid (contains varying amounts of Anhydride) → 5-Methyl-2-(4-trimethylsilanyl-phenyl)-pyridine
Reaktionsgleichung
[Br:14][c:15]1[n:16][cH:17][c:18]([CH3:21])[cH:19][cH:20]1.[C:22](=[O:23])([O-:24])[O-:25].[CH2:28]([P:29]([C:30]([CH3:31])([CH3:32])[CH3:33])[C:34]([CH3:35])([CH3:36])[CH3:37])[c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1.[CH3:1][Si:2]([c:3]1[cH:4][cH:5][c:6]([B:9]([OH:10])[OH:11])[cH:7][cH:8]1)([CH3:12])[CH3:13].[CH:46](=[CH:47][C:48]([CH:49]=[CH:50][c:51]1[cH:52][cH:53][cH:54][cH:55][cH:56]1)=[O:57])[c:58]1[cH:59][cH:60][cH:61][cH:62][cH:63]1.[CH:64](=[CH:65][C:66]([CH:67]=[CH:68][c:69]1[cH:70][cH:71][cH:72][cH:73][cH:74]1)=[O:75])[c:76]1[cH:77][cH:78][cH:79][cH:80][cH:81]1.[CH:82](=[CH:83][C:84]([CH:85]=[CH:86][c:87]1[cH:88][cH:89][cH:90][cH:91][cH:92]1)=[O:93])[c:94]1[cH:95][cH:96][cH:97][cH:98][cH:99]1.[Cs+:26].[Cs+:27].[O:100]1[CH2:101][CH2:102][O:103][CH2:104][CH2:105]1.[Pd:44].[Pd:45]>>[CH3:1][Si:2]([c:3]1[cH:4][cH:5][c:6](-[c:15]2[n:16][cH:17][c:18]([CH3:21])[cH:19][cH:20]2)[cH:7][cH:8]1)([CH3:12])[CH3:13]
