Triethyl orthoacetate → 1,1,1-Triethoxybutane

HRID 2049311

Reaktionsgleichung

Reaktionsgleichung von HRID 2049311
O=[C:2](C1SC=CC=1)[CH2:3]C#N.[C:11]([O:19][CH2:20][CH3:21])([O:16][CH2:17][CH3:18])([O:13][CH2:14][CH3:15])[CH3:12].CC1SC=C(C(=O)CC#N)C=1>>[C:11]([O:13][CH2:14][CH3:15])([O:16][CH2:17][CH3:18])([O:19][CH2:20][CH3:21])[CH2:12][CH2:2][CH3:3]

Komponenten

4

Edukt 3

HCID 66221Triethyl orthoacetateHCID 1418532-ThenoylacetonitrileHCID 203450545-Methyl-beta-oxo-3-thiophenepropionitrile

Produkt 1

HCID 3717791,1,1-Triethoxybutane

Versuchsvorschrift

The general procedure of Example 11 is repeated but replacing the β-oxo-2-thiophenepropionitrile and triethyl orthoacetate employed in that example with equivalent amounts of 5-methyl-β-oxo-3-thiophenepropionitrile and triethyl orthobutyrate whereby there is obtained the title compound in equally good yield.

Quellen und Nachweise

ORD-Eintrag
ord-f02fa6a482744ddf92cd3ffb5abf0761
Quelldatensatz
uspto-grants-1980_04
Patentnummer
US04197310

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