Acetone → HCID 12962350, Verbindung

HRID 2059112Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2059112
[C:1]1([CH:7]2[NH:11][CH2:10][CH2:9][S:8]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.CC(C)=O.C(N(CC)CC)C.[Cl:23][CH:24]([Cl:28])[C:25](Cl)=[O:26]>O>[C:1]1([CH:7]2[N:11]([C:25](=[O:26])[CH:24]([Cl:28])[Cl:23])[CH2:10][CH2:9][S:8]2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Komponenten

6

Edukt 4

HCID 180AcetoneHCID 6593Dichloroacetyl chlorideHCID 8471TriethylamineHCID 207062-Phenylthiazolidine

Produkt 1

HCID 12962350HCID 12962350, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

Five (5) grams of 2-phenyl thiazolidine was dissolved in 50 ml. of acetone, 3.1 g. of triethylamine was added and the mixture stirred in a room temperature water bath, while 4.4 g. of dichloroacetyl chloride was added dropwise. The mixture was allowed to stand for about 30 minutes and then poured into water, extracted with methylene chloride, separated, dried over magnesium sulfate, and the solvent stripped under vacuum. There was obtained a yield of 7.3 g. of an oil, the title compound, ND30 =1.5836.

Aufarbeitung

  1. extractionextracted with methylene chloride
  2. customseparated
  3. dry with materialdried over magnesium sulfate
  4. customThere was obtained a yield of 7.3 g

Quellen und Nachweise

ORD-Eintrag
ord-638d2d11e1034966beb0d7c0c17c56e7
Quelldatensatz
uspto-grants-1982_03
Patentnummer
US04322240

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