Allyl chloride → 2-Bromo-1-chloropropane
Reaktionsgleichung
[Br:1][CH2:2][CH2:3][CH2:4][Cl:5].[CH2:6]([Cl:9])[CH:7]=[CH2:8]>C1CCCCC1>[Br:1][CH2:2][CH2:3][CH2:4][Cl:5].[Br:1][CH:7]([CH3:8])[CH2:6][Cl:9]Komponenten
5
Edukt 2
Produkt 2
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
The same process as in example 2 was carried out, but the cyclohexane was replaced by 3-bromo-1-chloropropane. The reaction developed in the same way. After 30 minutes of irradiation at 22° C, 90% of allyl chloride had been converted. The reaction product was degassed and the unreacted allyl chloride was distilled. The remaining product was formed by 3-bromo-1-chloropropane (solvent + formed product) and about 3% of 2-bromo-1-chloropropane. This operation has the advantage of making the solvent distillation unnecessary.
Aufarbeitung
- customAfter 30 minutes of irradiation at 22° C
- customThe reaction product was degassed
- distillationthe unreacted allyl chloride was distilled
Quellen und Nachweise
- ORD-Eintrag
- ord-fd729aa701f2427aaa34fce67080442c
- Quelldatensatz
- uspto-grants-1977_09
- Patentnummer
- US04049516
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