Water → N-[(2,4,6-Trimethylbenzene-1-sulfonyl)oxy]propan-2-imine

HRID 2105290Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2105290
[C:1]1([CH3:13])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[S:9](Cl)(=[O:11])=[O:10].[CH3:14][C:15](=[N:17][OH:18])[CH3:16].O>N1C=CC=CC=1>[CH3:13][C:1]1[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[S:9]([O:18][N:17]=[C:15]([CH3:16])[CH3:14])(=[O:11])=[O:10]

Komponenten

5

Edukt 3

HCID 962WaterHCID 130462-Mesitylenesulfonyl chlorideHCID 67180Acetone, oxime

Produkt 1

HCID 279802N-[(2,4,6-Trimethylbenzene-1-sulfonyl)oxy]propan-2-imine

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 1049PyridineLösungsmittel

Versuchsvorschrift

To a solution of mesitylenesulfonyl chloride (2.0 g, 9.05 mmol) in pyridine (30 mL) was added acetone oxime (0.67 g, 9.05 mmol), and the solution was stirred under N2 for 16 hours. It was poured into 500 ml of water and stirred for 1 hour. The precipitate was filtered and dried. Acetone O-(2,4,6-trimethylphenylsulfonyl)oxime was obtained as white powder (57.6%) yield.

Aufarbeitung

  1. stirringstirred for 1 hour
  2. filtrationThe precipitate was filtered
  3. customdried

Quellen und Nachweise

ORD-Eintrag
ord-8deaa3c6c49246ac97ccd16d5fb37fbf
Quelldatensatz
uspto-grants-2009_08
Patentnummer
US07579340B2

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