Pivalaldehyde → [2-(tert-Butyl-dimethylsilanyloxy)-ethyl]-(2,2-dimethyl-propyl)-amine
Reaktionsgleichung
[Si:1]([O:8][CH2:9][CH2:10][NH:11]C1CCCC1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2].[CH3:17][C:18]([CH3:22])([CH3:21])[CH:19]=O.[Si](OCCN)(C(C)(C)C)(C)C>>[Si:1]([O:8][CH2:9][CH2:10][NH:11][CH2:19][C:18]([CH3:22])([CH3:21])[CH3:17])([C:4]([CH3:6])([CH3:7])[CH3:5])([CH3:3])[CH3:2]Komponenten
4
Versuchsvorschrift
This compound was prepared following the same method as described for [2-(tert-butyl-dimethylsilanyloxy)-ethyl]-cyclopentyl-amine (8e) from 2,2-dimethyl-propionaldehyde (1 g, 11.61 mmol) and 2-(tert-butyl-dimethylsilanyloxy)-ethylamine (8c) (2.0 g, 11.6 mmol) as colorless oil (1.1 g, 38.6%).