Piperonal → Bis(3,4-methylenedioxy)chalcone

HRID 2170271

Reaktionsgleichung

Reaktionsgleichung von HRID 2170271
[CH:1]1[C:6]([CH:7]=[O:8])=[CH:5][C:4]2[O:9][CH2:10][O:11][C:3]=2[CH:2]=1.[CH3:12][C:13]([C:15]1[CH:20]=[CH:19][C:18]2[O:21][CH2:22][O:23][C:17]=2[CH:16]=1)=O.[OH-].[Na+]>C(O)C>[CH2:22]1[O:21][C:18]2[CH:19]=[CH:20][C:15]([CH:13]=[CH:12][C:7]([C:6]3[CH:1]=[CH:2][C:3]4[O:11][CH2:10][O:9][C:4]=4[CH:5]=3)=[O:8])=[CH:16][C:17]=2[O:23]1

Komponenten

5

Edukt 3

HCID 8438PiperonalHCID 14798Sodium HydroxideHCID 76622Acetopiperone

Produkt 1

HCID 294346Bis(3,4-methylenedioxy)chalcone

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

A mixture of piperonal (460 mg) and 3,4-methylenedioxyacetophenone (500 mg) in ethanol (20 ml) was treated with 1M NaOH solution (4 ml), then the mixture was stirred overnight. The pale yellow crystalline solid was filtered off, washed with water then cold aqueous ethanol and dried to give pure bis(3,4-methylenedioxy)chalcone DC-0006B (476 mg, 53%).

Aufarbeitung

  1. filtrationThe pale yellow crystalline solid was filtered off
  2. washwashed with water
  3. dry with materialcold aqueous ethanol and dried

Quellen und Nachweise

ORD-Eintrag
ord-f07f4bc4c5814b05824736c9efcf4768
Quelldatensatz
uspto-grants-2015_06
Patentnummer
US09051253B2

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