Water → Cyclopropanesulphonylbenzene

HRID 2212062Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2212062
[C:1]1([S:7][CH:8]2[CH2:10][CH2:9]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH:11]OS([O-])=O.[K+].[OH2:17]>CO>[CH:8]1([S:7]([C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)(=[O:11])=[O:17])[CH2:10][CH2:9]1

Komponenten

5

Edukt 3

HCID 962WaterHCID 123348Cyclopropyl phenyl sulfideHCID 23707502Potassium hydroxy sulfite

Produkt 1

HCID 11309899Cyclopropanesulphonylbenzene

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

A solution of cyclopropyl phenyl sulfide (10.5 g, 70 mmol) and Oxone™ (55.13 g, 175 mmol) in methanol (30 ml) was stirred at room temperature for 5 hours. The mixture was diluted was water and extracted with ethyl acetate. The combined organic layers were dried (MgSO4) and concentrated in vacuo.

Aufarbeitung

  1. additionThe mixture was diluted
  2. extractionextracted with ethyl acetate
  3. dry with materialThe combined organic layers were dried (MgSO4)
  4. concentrationconcentrated in vacuo

Quellen und Nachweise

ORD-Eintrag
ord-cf85ed6b24364e7f880c4edaa04925ef
Quelldatensatz
uspto-grants-2006_09
Patentnummer
US07101892B2

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