Hydroxyamine hydrochloride → 5-[(1E)-1-hydroxyimino-2,3-dihydroinden-5-yl]-1-methylpyrrole-2-carbonitrile
Reaktionsgleichung
[CH3:1][N:2]1[C:6]([C:7]2[CH:8]=[C:9]3[C:13](=[CH:14][CH:15]=2)[C:12](=O)[CH2:11][CH2:10]3)=[CH:5][CH:4]=[C:3]1[C:17]#[N:18].Cl.[NH2:20][OH:21]>>[OH:21]/[N:20]=[C:12]1\[CH2:11][CH2:10][C:9]2[C:13]\1=[CH:14][CH:15]=[C:7]([C:6]1[N:2]([CH3:1])[C:3]([C:17]#[N:18])=[CH:4][CH:5]=1)[CH:8]=2Komponenten
3
Versuchsvorschrift
The title compound was prepared from 1-methyl-5-(1-oxo-2,3-dihydro-1H-inden-5-yl)-1H-pyrrole-2-carbonitrile and hydroxylamine hydrochloride according to the procedure described in example 1. MS (ESI) m/z 252; HRMS: calcd for C15H13N3O+H+, 252.11314; found (ESI, [M+H]+), 252.1133
Quellen und Nachweise
- ORD-Eintrag
- ord-458679afecbf4b4b9ee02162f71adcf8
- Quelldatensatz
- uspto-grants-2008_08