Sodium cyanoborohydride → HCID 67852533, Verbindung
Reaktionsgleichung
[NH2:1][C@H:2]([C:4]([N:6]1[CH:14]2[CH:9]([CH2:10][CH2:11][CH2:12][CH2:13]2)[CH2:8][C@H:7]1[C:15]([OH:17])=[O:16])=[O:5])[CH3:3].O=[C:19]([CH2:23][CH2:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[C:20]([NH2:22])=[O:21].C([BH3-])#N.[Na+]>>[NH2:22][C:20]([CH:19]([NH:1][C@H:2]([C:4]([N:6]1[CH:14]2[CH:9]([CH2:10][CH2:11][CH2:12][CH2:13]2)[CH2:8][C@H:7]1[C:15]([OH:17])=[O:16])=[O:5])[CH3:3])[CH2:23][CH2:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)=[O:21]Komponenten
4
Versuchsvorschrift
React 1-[(S)-alanyl]octahydroindole-2(S)-carboxylic acid (preparable as described in Example 1) and 2-oxo-4-phenylbutyramide and sodium cyanoborohydride to obtain the title compound as described in Example 5.
Quellen und Nachweise
- ORD-Eintrag
- ord-c604606b44864bcf90be35ee750393ae
- Quelldatensatz