1-Bromodecane → 5-Benzyloxy-2-(4-decyloxyphenyl)pyrimidine
Reaktionsgleichung
[CH2:1]([O:8][C:9]1[CH:10]=[N:11][C:12]([C:15]2[CH:20]=[CH:19][C:18]([OH:21])=[CH:17][CH:16]=2)=[N:13][CH:14]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Br[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32].CC(C)=CCCC1CCC(CCC2C=CC(OCC3CCC(CCCCC)=CC3)=CC=2)CC=1>>[CH2:1]([O:8][C:9]1[CH:14]=[N:13][C:12]([C:15]2[CH:16]=[CH:17][C:18]([O:21][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32])=[CH:19][CH:20]=2)=[N:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1Komponenten
4
Versuchsvorschrift
The reaction between 5-benzyloxy-2-(4-hydroxyphenyl)pyrimidine (prepared essentially according to the procedure of E. P. Janulis et al., U.S. Pat. No. 5,399,291) and bromodecane is essentially that used for synthesis of ether 2H.