HCID 54569294, Verbindung → 3-Hexylaniline

HRID 2232414Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2232414
[CH:1]([C:7]1[CH:8]=[C:9]([N+:13]([O-])=O)[CH:10]=[CH:11][CH:12]=1)=[CH:2][CH2:3][CH2:4][CH2:5][CH3:6].[H][H]>C(O)C.[Pd]>[CH2:1]([C:7]1[CH:8]=[C:9]([CH:10]=[CH:11][CH:12]=1)[NH2:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

Komponenten

5

Edukt 2

HCID 54569294HCID 54569294, VerbindungHCID 178418361HCID 178418361, Verbindung

Produkt 1

HCID 5722403-HexylanilineAusbeute 90,5 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23938PalladiumKatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

The 3-(1-hexenyl)nitrobenzene (11.0 g, 0.054 m) was dissolved in absolute ethanol (500 ml), treated with 1.1 g of 10% palladium on charcoal catalyst and hydrogenated on a Parr apparatus at about 45 psi for 21/2 hours. Hydrogen uptake had ceased. The reaction mixture was filtered to remove catalyst, concentrated under vacuum, and then resulting oil purified by Kuglrohr distillation (BP 75°-85° C. at 0.05 mm Hg) to yield 3-hexylaniline (8.6 g, 90% yield) as a clear colorless oil.

Aufarbeitung

  1. custom2 hours
  2. filtrationThe reaction mixture was filtered
  3. customto remove catalyst
  4. concentrationconcentrated under vacuum
  5. customresulting oil
  6. distillationpurified by Kuglrohr distillation (BP 75°-85° C. at 0.05 mm Hg)

Quellen und Nachweise

ORD-Eintrag
ord-12db25c0d34f4f5da099e60db4a9b429
Quelldatensatz
uspto-grants-1988_11
Patentnummer
US04788209

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