Hydrochloric Acid → HCID 54254998, Verbindung

HRID 223649

Reaktionsgleichung

Reaktionsgleichung von HRID 223649
[CH3:1][C:2]1([CH3:17])[CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([CH:14]([CH3:16])[CH3:15])[N:4]=[CH:3]1.Cl.Cl.[NH2:20][NH:21][C:22]([NH2:24])=[O:23]>O>[CH3:1][C:2]([CH3:17])([CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([CH:14]([CH3:16])[CH3:15])[NH2:4])[CH:3]=[N:20][NH:21][C:22]([NH2:24])=[O:23]

Komponenten

5

Edukt 3

HCID 313Hydrochloric AcidHCID 11236Semicarbazide hydrochlorideHCID 5575123,3-Dimethyl-12-isopropyl-1-aza-1,5,9-cyclododecatriene

Produkt 1

HCID 54254998HCID 54254998, VerbindungAusbeute 86 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

The procedure described in Example 1(b) is repeated, except that 23.3 g (0.1 mol) of 3,3-dimethyl-12-isopropyl-1-aza-1,5,9-cyclododecatriene, 20 g of 37% hydrochloric acid, 20 ml of water and 11.15 g (0.1 mol) of semicarbazide hydrochloride are used. Working up yields 26.5 g (0.086 mol) of 2,2-dimethyl-11-isopropyl-11-amino-undeca-4,8-dienal semicarbazone; yield 86% of theory.

Quellen und Nachweise

ORD-Eintrag
ord-9aa670777b5f407bba7fb02256f2d00a
Quelldatensatz
uspto-grants-1982_10
Patentnummer
US04355177

Verknüpfte Notizen

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