Sodium Hydroxide → HCID 86612200, Verbindung

HRID 225407

Reaktionsgleichung

Reaktionsgleichung von HRID 225407
C([O:9][CH:10]([C:18]([F:21])([F:20])[F:19])[C:11]([F:17])([F:16])[S:12]([O-:15])(=[O:14])=[O:13])(=O)C1C=CC=CC=1.[Na+:22].[OH-].[Na+]>O>[OH:9][CH:10]([C:18]([F:21])([F:19])[F:20])[C:11]([F:16])([F:17])[S:12]([O-:15])(=[O:14])=[O:13].[Na+:22]

Komponenten

4

Edukt 2

HCID 14798Sodium HydroxideHCID 58112889Sodium 2-benzoyloxy-1,1,3,3,3-pentafluoropropanesulfonate

Produkt 1

HCID 86612200HCID 86612200, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

In 43 g of water was dissolved 14.6 g of sodium 2-benzoyloxy-1,1,3,3,3-pentafluoro-propane-1-sulfonate synthesized in Synthesis Example 9. The solution was stirred under ice cooling. To the solution, 7.4 g of a 26% sodium hydroxide aqueous solution was added dropwise at a temperature below 10° C. The reaction solution was aged for 1 hour at the temperature and for a further 1 hour at room temperature. The solution was washed with toluene, from which an aqueous layer was separated. It was an aqueous solution of the target compound, sodium 2-hydroxy-1,1,3,3,3-pentafluoropropane-1-sulfonate. Without further isolation, the aqueous solution was directly analyzed by NMR spectroscopy and TOFMS for confirming the formation of the target compound.

Aufarbeitung

  1. customsynthesized in Synthesis Example 9
  2. washThe solution was washed with toluene, from which an aqueous layer
  3. customwas separated

Quellen und Nachweise

ORD-Eintrag
ord-3c218bf79fb64e18886b3b998cee6154
Quelldatensatz
uspto-grants-2009_07
Patentnummer
US07556909B2

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