Tetrahydrofuran → HCID 22033037, Verbindung

HRID 227389Notizen

Reaktionsgleichung

[CH2:1]([O:8][CH:9](O)[CH2:10][CH2:11][CH3:12])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(N(CC)CC)C.[CH3:21][S:22](Cl)(=[O:24])=[O:23].C1C[O:29]CC1>>[CH3:21][S:22]([O:24][CH2:12][CH2:11][CH2:10][CH2:9][O:8][CH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)(=[O:29])=[O:23]

Komponenten

Edukt 4

HCID 8028Tetrahydrofuran

HCID 8471Triethylamine

HCID 31297Methanesulfonyl chloride

HCID 198665521-Benzyloxy-1-butanol

Produkt 1

HCID 22033037HCID 22033037, Verbindung

Versuchsvorschrift

The 1-benzyloxy-1-butanol (Aldrich, 0.22 g, 1.2 mmol), triethylamine (0.56 mL, 4.1 mmol), and methanesulfonyl chloride (0.15 mL, 1.9 mmol) in 10 mL THF were processed as described in Example 1C to give the title compound that was used directly in the next reaction.

Quellen und Nachweise

ORD-Eintrag: ord-01ec4ccab9eb4909b61bf722dafeae4a
Quelldatensatz: uspto-grants-2009_07
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US07560481B2

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