Methyl triflate → HCID 15476282, Verbindung

HRID 2288572

Reaktionsgleichung

Reaktionsgleichung von HRID 2288572
[CH:1]1[C:14]2[C:5](=[N:6][C:7]3[C:12]([C:13]=2[C:15]([O:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[O:16])=[CH:11][CH:10]=[CH:9][CH:8]=3)[CH:4]=[CH:3][CH:2]=1.[O:24](C)[S:25]([C:28]([F:31])([F:30])[F:29])(=[O:27])=[O:26]>C(Cl)Cl>[F:29][C:28]([F:31])([F:30])[S:25]([O-:27])(=[O:26])=[O:24].[CH3:28][N+:6]1[C:5]2[C:14](=[CH:1][CH:2]=[CH:3][CH:4]=2)[C:13]([C:15]([O:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[O:16])=[C:12]2[C:7]=1[CH:8]=[CH:9][CH:10]=[CH:11]2

Komponenten

4

Edukt 2

HCID 9526Methyl triflateHCID 517916Phenyl acridine-9-carboxylate

Produkt 1

HCID 15476282HCID 15476282, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6344DichloromethaneLösungsmittel

Versuchsvorschrift

Phenyl acridine-9-carboxylate (530 mg, 1.7 mmol) was dissolved in CH2Cl2 (5 mL) under argon and methyl triflate (1 mL, 8.8 mmol) was added. The solution was stirred overnight at room temperature to yield a thick yellow precipitate. This precipitate was filtered, washed with ether and dried to obtain the product as yellow crystals. 1H NMR (acetone-d6) δ 5.22 (s, 3H), 7.47-7.71 (m, 5H), 8.23-9.07 (m, 8H).

Aufarbeitung

  1. customto yield a thick yellow precipitate
  2. filtrationThis precipitate was filtered
  3. washwashed with ether
  4. customdried

Quellen und Nachweise

ORD-Eintrag
ord-ccd31068837e4f0483912c6297c5bf4a
Quelldatensatz
uspto-grants-2000_07
Patentnummer
US06090571

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