Ammonia → Trioctylamine

HRID 232395

Reaktionsgleichung

[NH3:1].[CH2:2](O)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]>>[CH2:2]([N:1]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

Komponenten

Edukt 2

HCID 222Ammonia

HCID 9571-Octanol

Produkt 1

HCID 14227Trioctylamine

Versuchsvorschrift

Reacting n-octanol with ammonia in a molar ratio of 7:1 under the same reaction conditions gave tri-n-octylamine in a yield of over 95 mol%. The 2.5% by weight of di-n-octylamine formed at the same time were separated quantitatively from the reaction product, added to fresh feed and alkylated with octanol. The resulting reaction mixture likewise contained the secondary amine in amount of about 2% by weight, so that in the steady state where the secondary amine formed is being returned again and again the reaction to the tertiary amine was virtually quantitative.

Aufarbeitung

customunder the same reaction conditions

Quellen und Nachweise

ORD-Eintrag: ord-ca2396e2baf6400a856bcc200529eb2d
Quelldatensatz: uspto-grants-1989_07
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04851578

Verknüpfte Notizen

Wird geladen…