Ammonium → 4-[9-(t-Butyldimethylsilyloxy)-1-nonynyl]-4-hydroxy-7-methoxy-3-(4-methoxyphenyl)-3-methylthiochroman
Reaktionsgleichung
[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([O:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][C:14]#[CH:15])([CH3:16])[CH3:17].[CH2:18]([Li:19])[CH2:20][CH2:21][CH3:22].[CH3:23][O:24][c:25]1[cH:26][cH:27][c:28]2[c:33]([cH:34]1)[S:32][CH2:31][C:30]([CH3:35])([c:36]1[cH:37][cH:38][c:39]([O:42][CH3:43])[cH:40][cH:41]1)[C:29]2=[O:44].[Cl-:45].[NH4+:46].[O:47]1[CH2:48][CH2:49][CH2:50][CH2:51]1>>[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([O:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][C:14]#[C:15][C:29]1([OH:44])[c:28]2[cH:27][cH:26][c:25]([O:24][CH3:23])[cH:34][c:33]2[S:32][CH2:31][C:30]1([CH3:35])[c:36]1[cH:37][cH:38][c:39]([O:42][CH3:43])[cH:40][cH:41]1)([CH3:16])[CH3:17]
