Aniline → Aniline, N-(2,2,2-trifluoroethyl)-

HRID 2351251

Reaktionsgleichung

Reaktionsgleichung von HRID 2351251
FC(F)(F)S([O-])(=O)=O.[F:9][C:10]([F:20])([F:19])[CH2:11][I+]C1C=CC=CC=1.[NH2:21][C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1>C(Cl)Cl>[F:9][C:10]([F:20])([F:19])[CH2:11][NH:21][C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1

Komponenten

4

Edukt 2

HCID 6115AnilineHCID 10993805HCID 10993805, Verbindung

Produkt 1

HCID 9596Aniline, N-(2,2,2-trifluoroethyl)-Ausbeute 90,8 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6344DichloromethaneLösungsmittel

Versuchsvorschrift

250 mg (0.573 mmol) of (2,2,2-trifluoroethyl)phenyliodonium trifluoromethanesulfonate, 107 mg (1.15 mmol) of aniline and 5 ml of methylene chloride were reacted and worked up in the same manner as described in Reference Example 4 to obtain 91.1 mg of N-(2,2,2-trifluoroethyl)aniline as an oily substance. Yield, 92%.

Quellen und Nachweise

ORD-Eintrag
ord-5d456a4c84e6411aa1338919de3e5b1a
Quelldatensatz
uspto-grants-1989_10
Patentnummer
US04873027

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