Stannous Chloride → 4-(2-Amino-4-methylphenoxy)phenol
Reaktionsgleichung
[CH3:1][C:2]1[CH:15]=[CH:14][C:5]([O:6][C:7]2[CH:12]=[CH:11][C:10]([OH:13])=[CH:9][CH:8]=2)=[C:4]([N+:16]([O-])=O)[CH:3]=1.Cl[Sn]Cl>>[NH2:16][C:4]1[CH:3]=[C:2]([CH3:1])[CH:15]=[CH:14][C:5]=1[O:6][C:7]1[CH:8]=[CH:9][C:10]([OH:13])=[CH:11][CH:12]=1Komponenten
3
Versuchsvorschrift
The product from Example 122a (1.89 g, 7.71 mmol) was reduced with SnCl2 following the procedure from Example 1f giving the title compound as a white solid (1.42 g, 86%).
Quellen und Nachweise
- ORD-Eintrag
- ord-2dc9006f8b1344809fa96b9ced798347
- Quelldatensatz
- uspto-grants-2010_07
- Patentnummer
- US07763731B2
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