N-Hydroxyphthalimide → Cyclohexylbenzene
Reaktionsgleichung
ON1C(=O)C2=CC=CC=C2C1=O.[CH:13]1([C:19]2([CH:27]=[CH:26][CH:25]=[CH:24][CH2:23]2)C[O:21][OH:22])[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14]1.[CH:28]1([C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)[CH2:33][CH2:32][CH2:31][CH2:30][CH2:29]1>>[O-:21][OH:22].[CH:19]1([C:13]2[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=2)[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27]1.[CH:34]1([C:28]2[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=2)[CH2:35][CH2:36][CH2:37][CH2:38][CH2:39]1Komponenten
5
Versuchsvorschrift
0.3 mmol of N-hydroxyphthalimide and 0.6 mmol of 1-cyclohexylbenzyl hydroperoxide are added at a temperature of 110° C. to 30 mmol of cyclohexylbenzene in a round-bottomed flask having an attached reflux condenser. The reaction mixture is stirred for 8 hours at said temperature under an oxygen atmosphere of 1 bar. 1-cyclohexylbenzene hydroperoxide is obtained at a selectivity of 96.2% at a cyclohexylbenzene conversion rate of 28.6%.