4-Methoxyphenol → Urethane acrylate

HRID 23847

Reaktionsgleichung

Reaktionsgleichung von HRID 23847
[C:1]([O:5]CCO)(=[O:4])[CH:2]=[CH2:3].CC1C(N=C=O)=CC([N:16]=[C:17]=[O:18])=CC=1.C([O-])(=O)C.C([O-])(=O)C.C([Sn+2]CCCC)CCC.COC1C=CC(O)=CC=1.C([C:52]1C=C(C)C=C(C(C)(C)C)[C:53]=1[OH:63])(C)(C)C>>[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[NH2:16][C:17]([O:63][CH2:53][CH3:52])=[O:18]

Komponenten

6

Edukt 5

HCID 90154-MethoxyphenolHCID 11443Toluene 2,4-DiisocyanateHCID 131652-Hydroxyethyl acrylateHCID 314042,6-Di-tert-butyl-4-methylphenolHCID 9798523Di-n-butyl diacetoxy tin

Produkt 1

HCID 21863578Urethane acrylate

Reaktionsbedingungen

Temperatur
70 °C

Versuchsvorschrift

232 g (2 mol) of 2-hydroxyethyl acrylate (molecular weight 116) was placed in a flask equipped with a stirring blade, and with constant stirring, 174 g (1 mol) of TDI (2,4-tolylene diisocyanate) was added dropwise, with care taken over the generated heat, and the temperature was raised to 70° C. 1 g of dibutyl tin diacetate, 0.2 g of hydroquinone monomethyl ether and 1 g of 2,6-di-t-butyl-4-methylphenol were then added. Reaction was allowed to proceed at this temperature for 7 hours, and once the disappearance of NCO absorption had been confirmed via an infrared absorption spectrum, the reaction mixture was removed, yielding a urethane acrylate (A-Y) as the radical polymerizable oligomer (A). The number average molecular weight of the synthesized urethane acrylate (A-X) was 406.

Aufarbeitung

  1. customequipped with a stirring blade
  2. temperaturegenerated heat
  3. customReaction
  4. customonce the disappearance of NCO absorption
  5. customhad been confirmed via an infrared absorption spectrum
  6. customthe reaction mixture was removed

Quellen und Nachweise

ORD-Eintrag
ord-91ffcdba78dc4cfb9720d394e1a2c253
Quelldatensatz
uspto-grants-2005_02
Patentnummer
US06853788B2

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