Resorcinol → 2-(2,4-Dihydroxyphenyl)-4,6-bis(4-phenoxyphenyl)-1,3,5-triazine
Reaktionsgleichung
Cl[C:2]1[N:7]=[C:6]([C:8]2[CH:13]=[CH:12][C:11]([O:14][C:15]3[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=3)=[CH:10][CH:9]=2)[N:5]=[C:4]([C:21]2[CH:26]=[CH:25][C:24]([O:27][C:28]3[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=3)=[CH:23][CH:22]=2)[N:3]=1.[Cl-].[Al+3].[Cl-].[Cl-].[C:38]1([CH:45]=[CH:44][CH:43]=[C:41]([OH:42])[CH:40]=1)[OH:39]>ClC1C=CC=CC=1>[OH:39][C:38]1[CH:40]=[C:41]([OH:42])[CH:43]=[CH:44][C:45]=1[C:2]1[N:7]=[C:6]([C:8]2[CH:13]=[CH:12][C:11]([O:14][C:15]3[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=3)=[CH:10][CH:9]=2)[N:5]=[C:4]([C:21]2[CH:26]=[CH:25][C:24]([O:27][C:28]3[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=3)=[CH:23][CH:22]=2)[N:3]=1Komponenten
5
Edukt 3
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Reaktionsbedingungen
- Temperatur
- 85 °C
Versuchsvorschrift
A mixture of 5.9 gm of 2-chloro-4,6-bis(4-phenoxyphenyl)-1,3,5-triazine, 2.6 gm aluminum chloride and 1.6 gm of resorcinol in 25 ml chlorobenzene was heated under nitrogen at 85° C. for 3 hr. An additional 0.17 gm resorcinol was added, and the heating continued for another 1 hr. The reaction mixture was cooled to room temperature, and quenched with water. The precipitated product was filtered, washed with water, and dried to give 5.1 gm of crude 2-(2,4-dihydroxyphenyl)-4,6-bis(4-phenoxyphenyl)-1,3,5-triazine.
Aufarbeitung
- temperatureThe reaction mixture was cooled to room temperature
- customquenched with water
- filtrationThe precipitated product was filtered
- washwashed with water
- customdried
Quellen und Nachweise
- ORD-Eintrag
- ord-0d34b6db08104cc2be2d5ab8f0fe362b
- Quelldatensatz
- uspto-grants-2005_02
- Patentnummer
- US06855269B2
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