Hydrochloric Acid → Triphenylsulfonium succinic acid salt

HRID 2408884

Reaktionsgleichung

Reaktionsgleichung von HRID 2408884
[C:1]1([Si](OC)(OC)[O:8]C)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(O[Si](OCC)(OCC)OCC)C.C[Si](OCC)(OCC)OCC.CO[Si](CCC[CH:48]1[CH2:53][C:52](=[O:54])[O:51][C:49]1=[O:50])(OC)OC.C(O[Si](OCC)(OCC)CCCNC(=O)CCCO)C.Cl.C(OCC(O)C)C.[OH-].[C:84]1([S+:90]([C:97]2[CH:102]=[CH:101][CH:100]=[CH:99][CH:98]=2)[C:91]2[CH:96]=[CH:95][CH:94]=[CH:93][CH:92]=2)[CH:89]=[CH:88][CH:87]=[CH:86][CH:85]=1>O.C(O)C.CC(C)=O>[C:52]([O-:51])(=[O:54])[CH2:53][CH2:48][C:49]([O-:50])=[O:8].[C:97]1([S+:90]([C:84]2[CH:85]=[CH:86][CH:87]=[CH:88][CH:89]=2)[C:91]2[CH:96]=[CH:95][CH:94]=[CH:93][CH:92]=2)[CH:98]=[CH:99][CH:100]=[CH:101][CH:102]=1.[C:1]1([S+:90]([C:91]2[CH:92]=[CH:93][CH:94]=[CH:95][CH:96]=2)[C:84]2[CH:89]=[CH:88][CH:87]=[CH:86][CH:85]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Komponenten

12

Edukt 8

HCID 313Hydrochloric Acid2×HCID 6517TetraethoxysilaneHCID 152871-Ethoxy-2-propanolHCID 16241TriethoxymethylsilaneHCID 18137TrimethoxyphenylsilaneHCID 2760693N-(3-Triethoxysilylpropyl)-4-hydroxybutyramideHCID 115072162,5-Furandione, dihydro-3-[3-(trimethoxysilyl)propyl]-HCID 21909474Triphenylsulfanium hydroxide

Produkt 1

HCID 87066795Triphenylsulfonium succinic acid salt

Reagenzien, Katalysatoren, Lösungsmittel 3

HCID 180AcetoneLösungsmittelHCID 702EthanolLösungsmittelHCID 962WaterLösungsmittel

Versuchsvorschrift

4.73 of phenyltrimethoxysilane, 69.54 g of tetraethoxysilane, 16.92 g of methyltriethoxysilane, 0.14 g of trimethoxysilylpropyl succinic anhydride, 7.33 g of N-(3-triethoxysilylpropyl)-4-hydroxybutyramide, and 150 g of acetone were charged into a 500 ml flask to be dissolved and the resultant mixed solution was warmed while stirring the mixed solution with a magnetic stirrer to reflux. Next, 31.78 g of a 0.01 M hydrochloric acid aqueous solution was added to the mixed solution. The reaction was carried out for 240 minutes and then the resultant reaction solution was cooled down to room temperature. Then, 200 g of propylene glycol monoethyl ether was added to the reaction solution, and ethanol, water and hydrochloric acid being reaction by-products were distilled off under reduced pressure to obtain a hydrolysis-condensation product. To the hydrolysis-condensation product, 1.34 of a 10% by weight triphenylsulfonium hydroxide aqueous solution was added to obtain a triphenylsulfonium succinic acid salt-containing Si polymer. The obtained polymer corresponded to a polymer having five types of unit structures of Formula (3-32). The molecular weight Mw of the obtained polymer measured by GPC was found to be 1,500 in terms of polystyrene.

Aufarbeitung

  1. dissolutionto be dissolved
  2. additionthe resultant mixed solution
  3. temperaturewas warmed
  4. temperatureto reflux
  5. customthe resultant reaction solution
  6. distillationwere distilled off under reduced pressure
  7. customto obtain a hydrolysis-condensation product

Quellen und Nachweise

ORD-Eintrag
ord-082587f5a2e844aaa4abc8829286447e
Quelldatensatz
uspto-grants-2014_08
Patentnummer
US08815494B2

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