m-Chloroperbenzoic acid → 3-methylsulfinyl-N'-sulfamoylpropanimidamide

HRID 2413345

Reaktionsgleichung

Reaktionsgleichung von HRID 2413345
ClC1C=CC=C(C(OO)=[O:9])C=1.[S:12]([NH:16][C:17](=[NH:22])[CH2:18][CH2:19][S:20][CH3:21])(=[O:15])(=[O:14])[NH2:13]>C(Cl)(Cl)Cl.CO>[S:12]([NH:16][C:17](=[NH:22])[CH2:18][CH2:19][S:20]([CH3:21])=[O:9])(=[O:14])(=[O:15])[NH2:13]

Komponenten

5

Edukt 2

HCID 70297m-Chloroperbenzoic acidHCID 178503794HCID 178503794, Verbindung

Produkt 1

HCID 1785046403-methylsulfinyl-N'-sulfamoylpropanimidamide

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 887MethanolLösungsmittelHCID 6212ChloroformLösungsmittel

Versuchsvorschrift

A solution of commercial 80% pure m-chloroperbenzoic acid (5.4 g, 25 mmol) in chloroform (40 ml) was added dropwise to a solution of N-sulfamyl-3-(methylthio)propionamidine (4.94 g, 25 mmol) in methanol (50 ml) at room temperature. After stirring for two hours, the product was collected by filtration, analytically pure, to give 4.44 g, mp 141°-144°.

Aufarbeitung

  1. filtrationthe product was collected by filtration
  2. customanalytically pure, to give 4.44 g, mp 141°-144°

Quellen und Nachweise

ORD-Eintrag
ord-461e854f44064aca83215e2c4ef6b828
Quelldatensatz
uspto-grants-1985_01
Patentnummer
US04496737

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