Sodium Methoxide → HCID 54496620, Verbindung

HRID 2413449Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2413449
C[O-].[Na+].[Cl:4][C:5]1[CH:6]=[N:7][C:8]2[C:13]([CH:14]=1)=[CH:12][CH:11]=[C:10]([Cl:15])[C:9]=2[CH:16]=O>CO.C(O)C>[Cl:4][C:5]1[CH:6]=[N:7][C:8]2[C:13]([CH:14]=1)=[CH:12][CH:11]=[C:10]([Cl:15])[C:9]=2[CH:16]=[CH:16][C:9]1[C:10]([Cl:15])=[CH:11][CH:12]=[C:13]2[C:8]=1[N:7]=[CH:6][C:5]([Cl:4])=[CH:14]2

Komponenten

5

Edukt 2

HCID 10942334Sodium MethoxideHCID 13090787HCID 13090787, Verbindung

Produkt 1

HCID 54496620HCID 54496620, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 702EthanolLösungsmittelHCID 887MethanolLösungsmittel

Versuchsvorschrift

18 ml of a 15% strength solution of sodium methylate in methanol were added dropwise, at room temperature, to a suspension of 25.4 g of 3,7-dichloro-8-triphenylphosphoniummethylquinoline chloride and 11.3 g of 3,7-dichloro-8-formylquinoline in 150 ml of ethanol. The mixture was stirred for 2 hours, after which the yellow precipitate was filtered off under suction, treated with water and again filtered off under suction.

Aufarbeitung

  1. filtrationafter which the yellow precipitate was filtered off under suction
  2. additiontreated with water
  3. filtrationagain filtered off under suction

Quellen und Nachweise

ORD-Eintrag
ord-8841b6b409c7485da9c83fc3053ea8a7
Quelldatensatz
uspto-grants-1988_01
Patentnummer
US04717416

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