Sodium Iodide → HCID 13338380, Verbindung
Reaktionsgleichung
[CH3:1][CH:2]1[CH2:4][N:3]1[C:5]1[C:6]2[N:14]([CH3:15])[N:13]=[C:12]([CH3:16])[C:7]=2[N:8]=[C:9]([CH3:11])[N:10]=1.[I-].[Na+]>CC(C)=O>[CH3:15][N:14]1[C:6]2[C:5]3[N:10]([CH2:4][CH:2]([CH3:1])[N:3]=3)[C:9]([CH3:11])=[N:8][C:7]=2[C:12]([CH3:16])=[N:13]1Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
The above aziridine (4.4 g, 0.02 mol) in 50 ml of acetone is stirred under reflux with 3.5 g of sodium iodide for three hours and evaporated in vacuo. The residue is partitioned in 150 ml of methylene dichloride and 50 ml of 20% aqueous sodium carbonate solution. The organic layer is separated, dried (MgSO4) and evaporated in vacuo. The resulting solid is recrystallized from acetonitrile to give 2.5 g of the title compound, mp 169°-172° C.