Benzoyl Peroxide → HCID 59512232, Verbindung

HRID 2427690Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2427690
[CH3:1][O:2][C:3](=[O:13])[C:4]1[C:9]([CH3:10])=[CH:8][C:7]([Br:11])=[CH:6][C:5]=1[CH3:12].[Br:14]NC(=O)CCC(N)=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[CH3:1][O:2][C:3](=[O:13])[C:4]1[C:5]([CH3:12])=[CH:6][C:7]([Br:11])=[CH:8][C:9]=1[CH2:10][Br:14]

Komponenten

5

Edukt 3

HCID 7187Benzoyl PeroxideHCID 9834204N-BromosuccinamideHCID 23134395Methyl 4-bromo-2,6-diMethylbenzoate

Produkt 1

HCID 59512232HCID 59512232, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 5943Carbon TetrachlorideLösungsmittel

Versuchsvorschrift

A mixture of 4-bromo-2,6-dimethyl-benzoic acid methyl ester (3.4 g, 14.2 mmol), N-bromosuccinamide (2.5 g, 14.2 mmol), and benzoyl peroxide (0.060 g, 0.25 mmol) in carbon tetrachloride (50 mL) was heated at reflux until majority of ester was consumed (as analyzed by GC/MS). The resulting mixture was filtered and the filtrate concentrated to afford 4-bromo-2-bromomethyl-6-methyl-benzoic acid methyl ester. The product obtained was used without further purification.

Aufarbeitung

  1. temperaturewas heated
  2. customwas consumed (as analyzed by GC/MS)
  3. filtrationThe resulting mixture was filtered
  4. concentrationthe filtrate concentrated

Quellen und Nachweise

ORD-Eintrag
ord-366d452b7bcb49e6a1e17d0bbea967b4
Quelldatensatz
uspto-grants-2011_06
Patentnummer
US07968570B2

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