Hexafluoropropylene oxide → Perfluoropropionyl fluoride

Reaktionsgleichung

[F:1][C:2]([F:10])([F:9])[C:3]1([F:8])[O:7][C:4]1([F:6])F.[F-:11].[K+]>>[C:2]([C:3]([C:4]([F:6])=[O:7])([F:8])[F:11])([F:10])([F:9])[F:1]

Komponenten

Edukt 2

HCID 9883Hexafluoropropylene oxide

HCID 522689Potassium Fluoride

Produkt 1

HCID 67912Perfluoropropionyl fluoride

Versuchsvorschrift

CF3CF2COF (b.p. -28° C.) is prepared by flowing hexafluoropropylene oxide through a stainless steel reactor tube containing active carbon carrying 3% by weight of potassium fluoride kept at 150° C.

Aufarbeitung

customkept at 150° C.

Quellen und Nachweise

ORD-Eintrag: ord-b65d6505f0614a34959860af8391f9a2
Quelldatensatz: uspto-grants-1987_11
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04709060

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