Methanol → 3-(Tetradecyloxy)benzoic acid

HRID 247933Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 247933
C[O:2][C:3](=[O:25])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH:5]=1.[OH-].[K+].CO>O>[CH2:11]([O:10][C:6]1[CH:5]=[C:4]([CH:9]=[CH:8][CH:7]=1)[C:3]([OH:25])=[O:2])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]

Komponenten

5

Edukt 3

HCID 887MethanolHCID 14797Potassium HydroxideHCID 5152765Methyl 3-(tetradecyloxy)benzoate

Produkt 1

HCID 32623113-(Tetradecyloxy)benzoic acidAusbeute 93,1 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

The title compound is prepared by the procedure of Example 2 using 234 g of 3-(tetradecyloxy)benzoic acid methyl ester, 113.0 g of potassium hydroxide, 1 L of methyl alcohol and 120 ml of water. The solid residue is recrystallized from methyl alcohol/ethyl alcohol to give 209 g of the desired product.

Aufarbeitung

  1. customThe solid residue is recrystallized from methyl alcohol/ethyl alcohol

Quellen und Nachweise

ORD-Eintrag
ord-c6728a311c3441738020fdd38caaaa65
Quelldatensatz
uspto-grants-1993_05
Patentnummer
US05208247

Notizen zur Reaktion

Wird geladen…