HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 248309Erstellt: 24. Oktober 2026
(Diethylamino)sulfur trifluoride → HCID 178447877, Verbindung
https://huagongshe.com/reaction/248309
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | (Diethylamino)sulfur trifluoride | HCID 123472 | — |
| Edukt | (Trifluoromethyl)trimethylsilane | HCID 552549 | — |
| Edukt | Tetrabutylammonium Fluoride | HCID 2724141 | — |
| Edukt | HCID 178447904 | HCID 178447904 | — |
| Lösungsmittel | Tetrahydrofuran | HCID 8028 | — |
| Produkt | HCID 178447877 | HCID 178447877 | — |
Reaktionsschritte
A mixture of 10 mmol of 4-(trans-4-propylcyclohexyl)cyclohexanone, 11 mmol of trimethyl(trifluoromethyl)silane, 10 mmol of tetrabutylammonium fluoride and 50 ml of THF is stirred for 2 hours at 0° C. After customary work-up, the crude product is dissolved in 20 mml of THF, 10 mmol of DAST are added, and the mixture is heated to boiling. After customary work-up, the crude product is purified by chromatography and crystallization.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US05209868 |
|---|
| Quelldatensatz | uspto-grants-1993_05 |
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| ORD ID | ord-93000c1993c1467d8c958cf156ab0696 |
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| Quellennotiz | uspto-grants-1993_05 |
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