Sodium borohydride → HCID 54068979, Verbindung

HRID 258734Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 258734
[CH2:1]([O:7][C:8]1[CH:9]=[C:10]([CH:13]=[CH:14][C:15]=1[O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH:11]=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[BH4-].[Na+]>C(O)C>[CH2:1]([O:7][C:8]1[CH:9]=[C:10]([CH:13]=[CH:14][C:15]=1[O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH2:11][OH:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

Komponenten

4

Edukt 2

HCID 4311764Sodium borohydrideHCID 118229373,4-dihexyloxybenzaldehyde

Produkt 1

HCID 54068979HCID 54068979, VerbindungAusbeute 97,4 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

A mixture of 3,4-dihexoxybenzaldehyde (15.3 g., 0.05 M), sodium borohydride (1.85 g., 0.05 M) and ethanol (350 ml.) is stirred at room temperature for one hour and then concentrated in vacuo. The residue is dissolved in chloroform (500 ml.), the solution washed with water (4× 100 ml.), dried (Na2SO4) and evaporated under reduced pressure to give 3,4-dihexoxybenzyl alcohol (15.0 g.) as a pale yellow oil.

Aufarbeitung

  1. concentrationconcentrated in vacuo
  2. dissolutionThe residue is dissolved in chloroform (500 ml.)
  3. washthe solution washed with water (4× 100 ml.)
  4. dry with materialdried (Na2SO4)
  5. customevaporated under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-337c9a8c8979472684f793f70a37d6a1
Quelldatensatz
uspto-grants-1977_07
Patentnummer
US04034040

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